Far Hill Quarry
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Harpur Hill Quarry is a disused
limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...
quarry A quarry is a type of open-pit mine in which dimension stone, rock, construction aggregate, riprap, sand, gravel, or slate is excavated from the ground. The operation of quarries is regulated in some jurisdictions to reduce their envi ...
on
Harpur Hill Harpur Hill is a small village on the outskirts of Buxton, Derbyshire, England. It is in the Cote Heath ward of the High Peak Borough Council. It has a primary school, a park, a pub, a working men's club and a Methodist church. From 1938 to 19 ...
, Derbyshire, England. Limestone was extracted there from 1835 to 1952 for
lime burning A lime kiln is a kiln used for the calcination of limestone ( calcium carbonate) to produce the form of lime called quicklime (calcium oxide). The chemical equation for this reaction is : CaCO3 + heat → CaO + CO2 This reaction can take pla ...
at
lime kiln A lime kiln is a kiln used for the calcination of limestone (calcium carbonate) to produce the form of lime (material), lime called quicklime (calcium oxide). The chemical equation for this chemical reaction, reaction is :Calcium carbonate, Ca ...
s to produce
quicklime Calcium oxide (CaO), commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline, crystalline solid at room temperature. The broadly used term "''lime''" connotes calcium-containing inorganic ma ...
. The quarry was used by the
Royal Air Force The Royal Air Force (RAF) is the United Kingdom's air and space force. It was formed towards the end of the First World War on 1 April 1918, becoming the first independent air force in the world, by regrouping the Royal Flying Corps (RFC) and ...
as a chemical weapons storage depot during the
Second World War World War II or the Second World War, often abbreviated as WWII or WW2, was a world war that lasted from 1939 to 1945. It involved the vast majority of the world's countries—including all of the great powers—forming two opposin ...
, the largest such depot in the United Kingdom. Afterwards a number of captured German chemical munitions were disposed of at the site by burning, which was only partially successful. The RAF depot closed in 1960 and the site is now vacant. A small part of the abandoned quarry has flooded to become a
quarry lake A quarry lake is a lake that is formed after a quarry has been dug through a mining operation. Formation During the mining process, water must be emptied. But after the mining operation has been abandoned, groundwater is allowed to seep in, ...
. Its water has a very high pH, that is, it is very
alkali In chemistry, an alkali (; from ar, القلوي, al-qaly, lit=ashes of the saltwort) is a basic, ionic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a ...
ne, owing to the presence of
caustic Caustic most commonly refers to: * Causticity, a property of various corrosive substances ** Sodium hydroxide, sometimes called ''caustic soda'' ** Potassium hydroxide, sometimes called ''caustic potash'' ** Calcium oxide, sometimes called ''caus ...
chemicals that are leaching from the waste left from the lime burning. The lake water has a vivid blue colour due to the scattering of light by finely dispersed particles of calcium carbonate. Despite signs warning of the health risks the lake became a popular tourist destination and swimming spot. The local High Peak Borough Council dyed the water black in 2013, 2016 and 2020 in an attempt to deter swimmers.


History

The site near Harpur Hill, south of
Buxton Buxton is a spa town in the Borough of High Peak, Derbyshire, England. It is England's highest market town, sited at some above sea level.
, was worked as a limestone quarry. Small-scale
lime burning A lime kiln is a kiln used for the calcination of limestone ( calcium carbonate) to produce the form of lime called quicklime (calcium oxide). The chemical equation for this reaction is : CaCO3 + heat → CaO + CO2 This reaction can take pla ...
had taken place near Harpur Hill since at least the 1600s, initially around Grin Low near Poole's Cavern to the north, using
lime kiln A lime kiln is a kiln used for the calcination of limestone (calcium carbonate) to produce the form of lime (material), lime called quicklime (calcium oxide). The chemical equation for this chemical reaction, reaction is :Calcium carbonate, Ca ...
s to produce
quicklime Calcium oxide (CaO), commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline, crystalline solid at room temperature. The broadly used term "''lime''" connotes calcium-containing inorganic ma ...
by calcinating the limestone (mainly
Bee Low Limestones The Bee Low Limestones is a geologic formation in England. It preserves fossils dating back to the Carboniferous period Period may refer to: Common uses * Era, a length or span of time * Full stop (or period), a punctuation mark Arts, ent ...
) quarried nearby (that is, heating calcium carbonate to produce calcium oxide). A site beside the quarry was used for large-scale lime production from around 1835 to around 1952, using larger
shaft kiln A kiln is a thermally insulated chamber, a type of oven, that produces temperatures sufficient to complete some process, such as hardening, drying, or chemical changes. Kilns have been used for millennia to turn objects made from clay int ...
s and then a multi-chambered
Hoffmann kiln The Hoffmann kiln is a series of batch process kilns. Hoffmann kilns are the most common kiln used in production of bricks and some other ceramic products. Patented by German Friedrich Hoffmann for brickmaking in 1858, it was later used for lime ...
, operated by Buxton Lime Firms Ltd (later
Brunner Mond Brunner may refer to: Places * Brunner, New Zealand * Lake Brunner, New Zealand * Brunner Mine, New Zealand * Brunner, Houston, United States * Brunner (crater), lunar crater Other uses * Brunner (surname) * Brunner the Bounty Hunter, a character ...
from 1918, and then ICI from 1926). The Hoffmann lime kiln was demolished in 1980 to create space for an industrial estate. Large volumes of solid waste from the lime burning were dumped in tips nearby, creating spoil heaps contaminated with traces of quicklime and with ash from the coal used in the process. Water percolating through the waste leaches
calcium hydroxide Calcium hydroxide (traditionally called slaked lime) is an inorganic compound with the chemical formula Ca( OH)2. It is a colorless crystal or white powder and is produced when quicklime (calcium oxide) is mixed or slaked with water. It has m ...
and becomes
alkaline In chemistry, an alkali (; from ar, القلوي, al-qaly, lit=ashes of the saltwort) is a base (chemistry), basic, ionic compound, ionic salt (chemistry), salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as ...
."The Harpur Hill Site: its geology, evolutionary history and a catalogue of materials present"
A.E. Mildowski, R.P. Shaw and D.I. Stewart, 2013. British Geological Survey Commissioned Report, CR/13/104
The site was taken over by the
Royal Air Force The Royal Air Force (RAF) is the United Kingdom's air and space force. It was formed towards the end of the First World War on 1 April 1918, becoming the first independent air force in the world, by regrouping the Royal Flying Corps (RFC) and ...
(RAF) in 1938 for use as a depot for the storage of
chemical weapon A chemical weapon (CW) is a specialized munition that uses chemicals formulated to inflict death or harm on humans. According to the Organisation for the Prohibition of Chemical Weapons (OPCW), this can be any chemical compound intended as a ...
s. Poor weather delayed construction and the depot did not become operational until 1940. During the
Second World War World War II or the Second World War, often abbreviated as WWII or WW2, was a world war that lasted from 1939 to 1945. It involved the vast majority of the world's countries—including all of the great powers—forming two opposin ...
it was the largest chemical weapons storage depot in the country, covering some . After the war the site was occupied by an RAF unexploded ordnance disposal unit, known as an X station, and used for storage and disarmament of captured German chemical weapons and V-rocket warheads. The RAF disposed of chemical weapons, including
mustard gas Mustard gas or sulfur mustard is a chemical compound belonging to a family of cytotoxic and blister agents known as mustard agents. The name ''mustard gas'' is technically incorrect: the substance, when dispersed, is often not actually a gas, b ...
and
phosgene Phosgene is the organic chemical compound with the formula COCl2. It is a toxic, colorless gas; in low concentrations, its musty odor resembles that of freshly cut hay or grass. Phosgene is a valued and important industrial building block, espe ...
, by burning it with bleach on the surrounding hills. This proved unsustainable, as large quantities of smoke were produced and the destruction was incomplete. Some mustard gas escaped as a vapour and much of the nearby vegetation was killed. The site also housed an RAF Mountain Rescue team who attended air crashes across Derbyshire. The RAF depot closed down in 1960.


Blue lagoon

A
quarry lake A quarry lake is a lake that is formed after a quarry has been dug through a mining operation. Formation During the mining process, water must be emptied. But after the mining operation has been abandoned, groundwater is allowed to seep in, ...
, officially known as Hoffman Quarry but also known as the Blue Lagoon, at the site became a tourist attraction owing to its vivid turquoise-blue coloration. It has attracted visitors from across the country. The colour derives from the scattering of light by small particles of calcium carbonate that are
precipitating In an aqueous solution, precipitation is the process of transforming a dissolved chemical substance, substance into an insoluble solid from a Supersaturated solution, super-saturated solution. The solid formed is called the precipitate. In cas ...
within the water. The caustic quicklime dissolved in the water gives it a pH level of 11.3 (by comparison bleach has a pH of 12.3). Signs at the site state the water can cause "skin and eye irritations, stomach problems and fungal infections such as thrush" and that the quarry is known to contain car wrecks, dead animals, excrement and rubbish. The water is also extremely cold. Despite this the lake continued to be a popular destination visited by hundreds of people. Around 750 local people, concerned about the health risks, signed a petition to have the quarry drained and closed off. However the water was deemed too toxic to drain, as it would risk contaminating local water supplies. In order to deter swimmers the water was dyed black in 2013 by High Peak Borough Council, who acted after being unable to get in touch with the site's owner. The dye wore off by 2015 and the water returned to a blue coloration. The council redyed the lake in 2016 with a stronger mixture, but by October 2019 it showed signs of returning to a blue colour. In March 2020 the lake was dyed again following reports of people gathering there despite social distancing instructions issued by the British government to combat the
COVID-19 pandemic The COVID-19 pandemic, also known as the coronavirus pandemic, is an ongoing global pandemic of coronavirus disease 2019 (COVID-19) caused by severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2). The novel virus was first identif ...
. It was redyed by High Peak Borough Council and Derbyshire Fire and Rescue on 29 May after people flocked to the site for the bank holiday weekend (25 May). The police also coned off potential parking spaces in Harpur Hill. With people continuing to visit the site local farmers attempted to deter them by spreading pig and cow slurry across the surrounding land on 19 June 2020.


Incidents

Derbyshire Police found the body of a 44-year-old man at the quarry on 18 February 2019. The death was found not to be suspicious. On 29 September 2019 two firefighters from
Staffordshire Fire and Rescue Service Staffordshire Fire and Rescue Service is the statutory fire and rescue service responsible for fire protection, prevention, intervention and emergency rescue in the county of Staffordshire and unitary authority of Stoke-on-Trent. The county ha ...
were injured whilst carrying out rope rescue training at the quarry. One of them was hospitalised with life-changing injuries.


See also

*
Buxton lime industry The Buxton lime industry has been important for the development of the town of Buxton in Derbyshire, England, and it has shaped the landscape around the town. Geology The White Peak area of the Peak District is named after the limestone pla ...


References

{{EngvarB, date=April 2020 High Peak, Derbyshire Quarries in England Lakes of Derbyshire